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• W2017204959 abstract "We report the first atomic-resolution study by scanning tunneling microscopy (STM) of the γ′-Al2O3 film formed on the Ni3Al(111) surface at ∼1000–1100 K. STM images of this well-ordered oxide film reveal a hexagonal array of corrugations with an average interatomic spacing of 3.0±0.1 Å. The low-energy electron diffraction (LEED) pattern of the aluminum oxide film reveals the ordering of O2− ions in the surface. On the basis of LEED data and theoretical considerations, the corrugations in the STM atomic-resolution images are tentatively assigned to oxygen anions. Annealing the oxide prepared at ∼300 K to ∼1100 K results in the appearance of a metallic aluminum peak in the Auger electron spectra and a substantial increase in the Al(1396)/Ni(848) ratio, indicating aluminum segregation close to the surface." @default.
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• W2017204959 date "1999-12-01" @default.
• W2017204959 modified "2023-10-07" @default.
• W2017204959 title "STM atomic-scale characterization of the γ′-Al2O3 film on Ni3Al(111)" @default.
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• W2017204959 doi "https://doi.org/10.1016/s0039-6028(99)00951-6" @default.
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