Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017218017> ?p ?o ?g. }
- W2017218017 endingPage "3276" @default.
- W2017218017 startingPage "3269" @default.
- W2017218017 abstract "The keto–enol tautomeric equilibria of ethyl acetoacetate in supercritical (SC) CO2 with and without ethanol cosolvent were investigated over the pressure range from 75.9 to 185 bar at 308.2 K using UV-Vis spectroscopy. In order to obtain the local densities of solvent and cosolvent about the solute, we correlated the standard Helmholtz free energy of the tautomerization with a solvent parameter based on the Onsager reaction field theory. In both SC CO2 and SC CO2–ethanol, the local density enhancement of CO2 in the vicinity of the solute is most remarkable at the reduced density close to unity. The highest degree of aggregation of cosolvent about the solute takes place at the lowest pressure investigated, which is slightly above the critical pressure. Moreover, the clustering of ethanol with the solute competes with that of CO2. In addition, the local concentration enhancement of ethanol was studied in the concentration range of 0 to 6 mol%. It was found that the local concentration of ethanol is enhanced significantly at lower cosolvent concentrations." @default.
- W2017218017 created "2016-06-24" @default.
- W2017218017 creator A5000490511 @default.
- W2017218017 creator A5038912290 @default.
- W2017218017 creator A5078750315 @default.
- W2017218017 date "1999-01-01" @default.
- W2017218017 modified "2023-10-10" @default.
- W2017218017 title "UV-Vis spectroscopic studies of solute–solvent and solute–cosolvent interactions in supercritical carbon dioxide" @default.
- W2017218017 cites W1964841227 @default.
- W2017218017 cites W1978121709 @default.
- W2017218017 cites W1983099419 @default.
- W2017218017 cites W1991974423 @default.
- W2017218017 cites W1995133646 @default.
- W2017218017 cites W1998987361 @default.
- W2017218017 cites W1999862544 @default.
- W2017218017 cites W2001217828 @default.
- W2017218017 cites W2005873869 @default.
- W2017218017 cites W2009518031 @default.
- W2017218017 cites W2016755032 @default.
- W2017218017 cites W2017843711 @default.
- W2017218017 cites W2018119586 @default.
- W2017218017 cites W2019288581 @default.
- W2017218017 cites W2022721980 @default.
- W2017218017 cites W2024931042 @default.
- W2017218017 cites W2025559155 @default.
- W2017218017 cites W2025653716 @default.
- W2017218017 cites W2027530049 @default.
- W2017218017 cites W2028847633 @default.
- W2017218017 cites W2030113025 @default.
- W2017218017 cites W2040162103 @default.
- W2017218017 cites W2040841079 @default.
- W2017218017 cites W2040969358 @default.
- W2017218017 cites W2043812411 @default.
- W2017218017 cites W2044111889 @default.
- W2017218017 cites W2045302996 @default.
- W2017218017 cites W2048638527 @default.
- W2017218017 cites W2049800650 @default.
- W2017218017 cites W2056591030 @default.
- W2017218017 cites W2058739323 @default.
- W2017218017 cites W2063801479 @default.
- W2017218017 cites W2066628480 @default.
- W2017218017 cites W2069297231 @default.
- W2017218017 cites W2071160760 @default.
- W2017218017 cites W2072421525 @default.
- W2017218017 cites W2073210336 @default.
- W2017218017 cites W2075614049 @default.
- W2017218017 cites W2079713298 @default.
- W2017218017 cites W2080571207 @default.
- W2017218017 cites W2080692877 @default.
- W2017218017 cites W2080987850 @default.
- W2017218017 cites W2082662238 @default.
- W2017218017 cites W2086796652 @default.
- W2017218017 cites W2087081667 @default.
- W2017218017 cites W2089575779 @default.
- W2017218017 cites W2091815381 @default.
- W2017218017 cites W2092700896 @default.
- W2017218017 cites W2102264915 @default.
- W2017218017 cites W2127284897 @default.
- W2017218017 cites W2140679147 @default.
- W2017218017 cites W2153706306 @default.
- W2017218017 cites W2160970795 @default.
- W2017218017 cites W2169094578 @default.
- W2017218017 cites W2326203395 @default.
- W2017218017 cites W2331522616 @default.
- W2017218017 cites W2592442340 @default.
- W2017218017 cites W2949437558 @default.
- W2017218017 cites W2953290869 @default.
- W2017218017 cites W3000235355 @default.
- W2017218017 doi "https://doi.org/10.1039/a901854i" @default.
- W2017218017 hasPublicationYear "1999" @default.
- W2017218017 type Work @default.
- W2017218017 sameAs 2017218017 @default.
- W2017218017 citedByCount "27" @default.
- W2017218017 countsByYear W20172180172014 @default.
- W2017218017 countsByYear W20172180172021 @default.
- W2017218017 crossrefType "journal-article" @default.
- W2017218017 hasAuthorship W2017218017A5000490511 @default.
- W2017218017 hasAuthorship W2017218017A5038912290 @default.
- W2017218017 hasAuthorship W2017218017A5078750315 @default.
- W2017218017 hasConcept C111233374 @default.
- W2017218017 hasConcept C113196181 @default.
- W2017218017 hasConcept C118419359 @default.
- W2017218017 hasConcept C121332964 @default.
- W2017218017 hasConcept C134458231 @default.
- W2017218017 hasConcept C153294291 @default.
- W2017218017 hasConcept C178790620 @default.
- W2017218017 hasConcept C185592680 @default.
- W2017218017 hasConcept C188721877 @default.
- W2017218017 hasConcept C2780161600 @default.
- W2017218017 hasConcept C2780471494 @default.
- W2017218017 hasConcept C530467964 @default.
- W2017218017 hasConcept C97355855 @default.
- W2017218017 hasConceptScore W2017218017C111233374 @default.
- W2017218017 hasConceptScore W2017218017C113196181 @default.
- W2017218017 hasConceptScore W2017218017C118419359 @default.
- W2017218017 hasConceptScore W2017218017C121332964 @default.
- W2017218017 hasConceptScore W2017218017C134458231 @default.
- W2017218017 hasConceptScore W2017218017C153294291 @default.