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- W2017219151 abstract "The cyclic polydentate thioether 1,3,5-trithiane reacts with the tetrahedral RuCo clusters [H4Ru4(CO)12], [H3Ru3Co(CO)12], [HRuCo3(CO)12] and [Co4(CO)12] by displaying either carbonyl or hydride ligands. The ligand can adopt various coordination modes, the choice of which can be affected by the reaction conditions. In refluxing THF a butterfly cluster [H2Ru4(CO)12(η1-μ2-trithiane)] (1) and a disubstituted [H4Ru4(CO)10(η2-trithiane)] (2) are the main products from the parent cluster [H4Ru4(CO)12]. In refluxing hexane or heptane the trisubstituted derivatives [H2Ru4(CO)10(η3-(trithiane)] (3), [HRu3Co(CO)10(η3-trithiane)] (4), [HRuCo3(CO)9(η3-trithiane)] (5) and [Co4(CO)9(η3-trithiane)] (6) are formed from the corresponding parent clusters [HxRuxCo4-x(CO)12] (x = 0, 1, 3, 4). The crystal structures of 1, 2, 3, 4 and 5 have been established. Trithiane prefers coordination at cobalt in the mixed metal clusters." @default.
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- W2017219151 date "1992-09-01" @default.
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- W2017219151 title "Reactions of 1,3,5-trithiacyclohexane with tetrahedral ruthenium-cobalt clusters" @default.
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- W2017219151 doi "https://doi.org/10.1016/0022-328x(92)85026-s" @default.
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