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- W2017219997 abstract "A short and efficient stereoselective total synthesis of (±)-7-deoxy-trans-dihydronarciclasine, a highly potent antineoplastic agent and constituent of the Amaryllidaceae alkaloids, is described. Starting from a known arylcyclohexylamine-type precursor 6, the C-ring with the required stereochemistry is constructed using a chemo- and stereoselective enone reduction (NaBH4/CaCl2 system) and a Mitsunobu reaction. For the B-ring closure, the Banwell modification of the Bischler–Napieralski reaction was applied." @default.
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- W2017219997 date "2009-06-01" @default.
- W2017219997 modified "2023-10-18" @default.
- W2017219997 title "Stereoselective total synthesis of (±)-7-deoxy-trans-dihydronarciclasine, a potent antineoplastic phenanthridone alkaloid" @default.
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- W2017219997 doi "https://doi.org/10.1016/j.tetlet.2009.03.162" @default.
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