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- W2017223859 abstract "The closely related, narrowly non-stoichiometric, metastable as well as thermodynamically stable “phases” in the metal-rich part of the Ni–S phase diagram near the nominal composition Ni7±xS6 have been carefully re-investigated via electron diffraction and transmission electron microscope imaging. Two quite distinct polymorphs have been identified, a minority incommensurate interface-modulated polymorph and a (heavily twinned) majority I1a1, a=2ap, b=2bp, c=−ap+cp superstructure (of an underlying Bmmb, ap∼3.3, bp∼16.4, cp∼11.3 Å parent structure) polymorph. The incommensurate polymorph is shown to be very closely related to the only known polymorph of Ni6±xSe5 and is rapidly stabilized to room temperature upon doping of the sulfide compounds with selenium." @default.
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- W2017223859 date "1992-01-01" @default.
- W2017223859 modified "2023-09-25" @default.
- W2017223859 title "Electron microscopy study of some Ni-S phases" @default.
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- W2017223859 doi "https://doi.org/10.1016/0739-6260(92)90126-x" @default.
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