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• W2017227669 abstract "Seven-coordinated molybdenum oxobisperoxo complexes with chelate nitrogen donors like pyrazolylpyridines are catalysts for the epoxidation of olefins. An NMR spectroscopic and quantumchemical study on the fluxionality of the chelate ligand proves that during this process partial ligand dissociation takes place. This gave rise to a detailed theoretical study on the activation of CH3OOH at the model complex (NH3)2MoO(O2)2 including dissociation of one of the ammonia ligands and proton transfer from the hydroperoxide to one of the peroxo ligands." @default.
• W2017227669 created "2016-06-24" @default.
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• W2017227669 date "2000-05-01" @default.
• W2017227669 modified "2023-10-10" @default.
• W2017227669 title "New Insights into the Mechanism of Hydroperoxide Activation by Investigation of Dynamic Processes in the Coordination Sphere of Seven-Coordinated Molybdenum Peroxo Complexes" @default.
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• W2017227669 doi "https://doi.org/10.1002/(sici)1099-0682(200005)2000:5<1107::aid-ejic1107>3.0.co;2-e" @default.
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