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- W2017230263 abstract "We report the results of magnetic measurements on a powder sample of NiCu(pba)(D_2O)_3 cdot 2D_2O$ (pba=1,3-propylenebis(oxamato)) which is one of the prototypical examples of an $S$=1/2 and 1 ferrimagnetic chain. Susceptibility($chi$) shows a monotonous increase with decreasing temperature (T) and reaches a maximum at about 7 K. In the plot of $chi T$ versus $T$, the experimental data exhibit a broad minimum and are fit to the $chi T$ curve calculated for the ferrimagnetic Heisenberg chain composed of S=1/2 and 1. From this fit, we have evaluated the nearest-neighbor exchange constant $J/k_B=121 K$, the g-values of Ni$^{2+}$ and Cu$^{2+}$, $g_{Ni}$=2.22 and $g_{Cu}$=2.09, respectively. Applied external field dependence of $chi T$ at low temperatures is reproduced fairly well by the calculation for the same ferrimagnetic model." @default.
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- W2017230263 title "Magnetic Properties of a Quantum Ferrimagnet: NiCu(pba)(<b><i>D</i></b><sub><b>2</b></sub><b><i>O</i></b>)<sub><b>3</b></sub>·<b>2<i>D</i></b><sub><b>2</b></sub><b><i>O</i></b>" @default.
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- W2017230263 doi "https://doi.org/10.1143/jpsj.67.2209" @default.
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