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- W2017233103 abstract "The Birch reduction of 10b,10c-dimethyl-10b,10c-dihydropyrene 1 and anthracene could be predicted on the basis of their reduction potentials and achieved readily with aqueous titanium trichloride in near quantitative yields. Controlled reduction of a nitro group could be achieved under these conditions with the aromatic hydrocarbon remaining intact. The anion derived from the hexane obtained from reduction of 1 provided synthetic routes to derivatives of 1 inaccessible from direct substitution reactions of 1. Oxidative dimerization of the anion led to the formation of a series of interesting products." @default.
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- W2017233103 title "A novel Birch reduction of aromatic compounds using aqueous titanium trichloride: anions of trans-10b,10c-dimethyl-2,7,10b,10c-tetrahydropyrene" @default.
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- W2017233103 doi "https://doi.org/10.1016/s0040-4039(02)02785-5" @default.
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