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- W2017233689 abstract "The conductivities of the binary room-temperature molten salt (RTMS) systems ZnCl 2 -N-nbutylpyridinium chloride (BPC), ZnCl 2 -1-ethyl-3-methylimidazolium chloride (EMIC) and ZnCl 2 - benzyltriethylammonium chloride (BTEAC) have been measured at different temperatures and compositions by a d.c. four-probes method. The conductivities of the three RTMS are in the order ZnCl 2 -EMIC > ZnCl 2 -BPC > ZnCl 2 -BTEAC. In ZnCl 2 -BPC the conductivity at 70 to 150 °C, is maximal for 40 mol% ZnCl 2 . In ZnCl 2 - EMIC, the conductivity below 130 °C is almost constant for 30 to 50 mol% ZnCl 2 and has the lowest activation energy 25.21 kJ/mol. For these two systems, the conductivities decrease rapidly beyond 50 mol% ZnCl 2 owing to the rapid increase in cross-linking and resultant tightening of the polyelectrolyte structure. As to the ZnCl2-BTEAC system, the conductivities at 110 - 150 °C decrease slowly for 30 - 60 mol% ZnCl 2 . The conductivities of the ZnCl 2 -EMICmelt are compared with those of the AlCl 3 -EMIC melt previously studied. The stability of the ZnCl 2 -EMIC melt system is explored by the effect of the environment on the conductivity and the Far Transmission Infra Red (FTIR) spectrum. It reveals that the effect is slight, and that the ZnCl 2 -EMIC melt may be classified as stable." @default.
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- W2017233689 date "2002-04-01" @default.
- W2017233689 modified "2023-09-26" @default.
- W2017233689 title "Conductivities of Room Temperature Molten Salts Containing ZnCl2, Measured by a Computerized Direct Current Method" @default.
- W2017233689 doi "https://doi.org/10.1515/zna-2002-3-404" @default.
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