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• W2017236889 abstract "Gas separation properties of polymer membrane materials follow distinct tradeoff relations: more permeable polymers are generally less selective and vice versa. Robeson1 identified the best combinations of permeability and selectivity for important binary gas pairs (O2/N2, CO2/CH4, H2/N2, etc.) and represented these permeability/selectivity combinations empirically as αA/B = βA/B , where PA and PB are the permeability coefficients of the more permeable and less permeable gases, respectively, αA/B is selectivity (=PA/PB), and λA/B and βA/B are empirical parameters. This report provides a fundamental theory for this observation. In the theory, λA/B depends only on gas size. βA/B depends on λA/B, gas condensability, and one adjustable parameter." @default.
• W2017236889 created "2016-06-24" @default.
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• W2017236889 date "1999-01-01" @default.
• W2017236889 modified "2023-10-17" @default.
• W2017236889 title "Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes" @default.
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• W2017236889 doi "https://doi.org/10.1021/ma9814548" @default.
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