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• W2017241694 abstract "The stability constants have been determined potentiometrically for the ternary copper(II)-amine-amino acid systems, where amine refers to ethylenediamine(en), N,N′-dimethylethylenediamine(dmen), N,N,N′,N′-tetramethylethylenediamine(tmen), or N,N′-dibenzylethylenediamine(dben), and amino acid to L-alanine(ala), L-valine(val), L-phenylalanine(phe), L-tyrosine(tyr), O-methyl-L-tyrosine(mtyr), L-tryptophan(trp), or 5-hydroxy-L-tryptophan(htrp). The tendency of the ternary complex formation (Δlog K) decreased in the order, dben > tmen > dmen > en for the amines and htrp ⋍ trp >tyr ⋍ mtyr ⋍ phe > val ⋍ ala for the amino acids. The preferred ternary complex formation of the systems containing dben or htrp was comparable with that observed for phenanthroline. The stability enhancement was found to be additive and proportional to the aromatic ring size. These observations suggest that the proximity of an aromatic ring around the copper(II) ion increases the electronegativity of copper(II) by both the copper(II)-aromatic ring interaction and decreased hydration." @default.
• W2017241694 created "2016-06-24" @default.
• W2017241694 creator A5049943075 @default.
• W2017241694 creator A5069425948 @default.
• W2017241694 date "1984-09-01" @default.
• W2017241694 modified "2023-10-16" @default.
• W2017241694 title "Preferential formation of ternary copper(II) complexes involving substituted ethylenediamines and amino acids with an aromatic side chain" @default.
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• W2017241694 doi "https://doi.org/10.1016/s0020-1693(00)85951-4" @default.
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