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- W2017246497 abstract "The first photochemical synthesis of some 1-carbaldehydobicyclo[n.1.0]alkane oxime acetates has been achieved by the aza-di-π-methane (ADPM) rearrangement of oxime acetates of 2-(cyclopent-1-enyl)- and 2-(cyclohex-1-enyl)-2-methylpropanals. Further increase in ring-size affects adversely the reaction and the oxime acetate of 2-(cyclohept-1-enyl)-2-methylpropanal is unreactive by the ADPM path. The low efficiency of rearrangement of 2-(cyclohex-1-enyl)-2-methylpropanal can be overcome by incorporation of a benzo substituent and this compound, 2-(2-[3,4-dihydronaphthalenyl])-2-methylpropanal, undergoes the ADPM rearrangement efficiently." @default.
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- W2017246497 title "Photochemical synthesis of oxime acetates derivatives of 1-carbaldehydobicyclo[n.1.0]alkanes by the aza-di-π-methane rearrangement." @default.
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- W2017246497 doi "https://doi.org/10.1016/s0040-4020(01)87986-2" @default.
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