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- W2017248317 abstract "An anion-imprinted material with high performance for recognizing chromate anion was prepared by adopting the novel molecule surface-imprinting technique put forward by our research group previously. Functional macromolecule polyvinylimidazole (PVI) was first grafted on the surfaces of micron-sized silica gel particles, forming the grafted particle PVI/SiO2. Afterwards, the ion imprinting was carried out towards the grafted macromolecule PVI by using CrO42− anion as template and 1,6-dibromohexane as crosslinking agent, and chromate ion surface-imprinted material IIP-PVI/SiO2 was obtained. The binding characteristic of IIP-PVI/SiO2 towards CrO42− anion was studied with both static and dynamic methods. The experimental results show that IIP-PVI/SiO2 has excellent binding affinity and high recognition selectivity for chromate anion. Before imprinting, the grafted particles PVI/SiO2 have similar adsorption capacities for both two anions, chromate anion and phosphate anion that was used as a contrast anion. However, after imprinting, the binding capacity of IIP-PVI/SiO2 towards phosphate anion decreases remarkably, whereas the binding capacity of IIP-PVI/SiO2 for chromate anion still remains very high, leading to a high selectivity coefficient (7.78) of IIP-PVI/SiO2 for CrO42− anion with respect of PO43− ion." @default.
- W2017248317 created "2016-06-24" @default.
- W2017248317 creator A5039953489 @default.
- W2017248317 creator A5070592637 @default.
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- W2017248317 date "2013-07-01" @default.
- W2017248317 modified "2023-09-27" @default.
- W2017248317 title "Preparation of chromate anion surface-imprinted material IIP-PVI/SiO2 based on polyvinylimidazole-grafted particles PVI/SiO2 and its ionic recognition characteristic" @default.
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- W2017248317 doi "https://doi.org/10.1016/j.matchemphys.2013.03.056" @default.
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