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- W2017249605 abstract "Cinchona alkaloid derivatives with natural configuration at C-3 have been constructed by Grignard reaction of protected rubanone 1-TBDS. The organomagnesium reagent attacks preferentially from the sterically more hindered endo face. Even L-Selectride® reacts endo-selectively (9 : 1)." @default.
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- W2017249605 title "Diastereocontrol of nucleophilic attack of the rubanone carbonyl group via remote siloxy tether. Establishing the natural configuration at carbon C-3 of Cinchona alkaloids" @default.
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