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- W2017253919 abstract "at several temperatures and activation parameters were determined. The thirty kinds of solvents gave a reasonably precise extended Grunwald-Winstein plot, coefficient (R) of 0.954. The sensitivity values (l = 0.61 and m = 0.34, l/m = 1.8) of phenyl methanesulfonyl chloride (I) were smaller than those obtained for benzenesulfonyl chloride (C6H5SO2Cl, II; l = 1.01 and m = 0.61) and 2-propanesulfonyl chloride ((CH3)2CHSO2Cl, III; l = 1.28 and m = 0.64). As with the two previously studied solvolyses, an SN2 pathway with somewhat ionization reaction is proposed for the solvolyses of I. The activation parameters, ΔH ≠ and ΔS ≠ , were determined and they are also in line with values expected for a bimolecular reaction mechanism. The kinetic solvent isotope effect of 2.34 in CH3OH/CH3OD is in accord with a bimolecular mechanism, probably assisted by general-base catalysis." @default.
- W2017253919 created "2016-06-24" @default.
- W2017253919 creator A5054062795 @default.
- W2017253919 creator A5066992992 @default.
- W2017253919 date "2011-06-20" @default.
- W2017253919 modified "2023-09-24" @default.
- W2017253919 title "Application of the Extended Grunwald-Winstein Equation to the Solvolyses of Phenyl Methanesulfonyl Chloride in Aqueous Binary Mixtures" @default.
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- W2017253919 doi "https://doi.org/10.5012/bkcs.2011.32.6.1897" @default.
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