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- W2017262932 abstract "For the first time combined X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD) experiments were carried out to probe the short- and long-range order in lanthanum-modified PbTiO3 ceramic materials (Pb1-xLaxTiO3) for x ranging from 0 to 30 atom % of La. XRD results show that a tetragonal structure fitted well to all samples, except to the one with 30 atom % of La for which XRD results highlighted a cubic unit cell. XRD refinements also confirmed the existence of only A-site vacancies. X-ray absorption near edge spectroscopy (XANES) measurements indicate that the local structure around Ti atoms has a different compositional dependence from the one obtained from XRD, mainly for the sample with 30 atom % of La. According to XANES data, for the sample with 30 atom % of La, a local distortion around Ti atoms persist. The analysis of extended X-ray absorption fine structure (EXAFS) spectra shows a decrease in the local disorder around Ti atoms as the content of La increases. Structural details, in terms of short and long-range order, are presented and the correlation between the XRD and XANES/EXAFS data is discussed." @default.
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- W2017262932 date "2004-09-01" @default.
- W2017262932 modified "2023-10-01" @default.
- W2017262932 title "XAS and XRD Structural Characterization of Lanthanum-Modified PbTiO<sub>3</sub> Ceramic Materials" @default.
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- W2017262932 doi "https://doi.org/10.1021/jp037166h" @default.
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