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• W2017266711 abstract "The multidentate Lewis acids B-octamethyl [12]-mercuracarborand-4 (1) and B-hexamethyl [9]-mercuracarborand-3 (2) catalyze the Diels-Alder reaction of a thionoester 4 with cyclopentadiene. The reaction proceeds more rapidly when catalyzed with 1 and 2 than with monodentate bis(closo-9,12-dimethyl-1,2-carboran-1-yl)mercury (3). Mercury-199 NMR studies demonstrated the formation of a 1:1 complex of 1 with 4 in which the thio function of 4 is coordinated to the Hg(II) centers of 1, while the 2·4 and 3·4 complexes are not observed by NMR." @default.
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• W2017266711 date "1999-10-01" @default.
• W2017266711 modified "2023-10-10" @default.
• W2017266711 title "Mercuracarborand-catalyzed Diels-Alder reactions of a thionoester with cyclopentadiene" @default.
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• W2017266711 doi "https://doi.org/10.1016/s0040-4039(99)01582-8" @default.
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