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• W2017284893 startingPage "6266" @default.
• W2017284893 abstract "High pressure (HP), high resolution (HR), proton nuclear magnetic resonance (1H NMR) spectroscopy has been utilized for the first time to investigate the solution structure of a carbohydrate based system, sucrose octaacetate (SOA), in supercritical CO2. The studies indicate that the average solution state conformation of the alpha-D-Glucopyranosyl ring of SOA in scCO2 medium is consistent with the 4C1 chair form, while the beta-D-fructofuranosyl ring adopts an envelope conformation. The investigations also suggest that scCO2 is a promising medium to study the solution structure and conformation of acetylated sugar systems. Spectral manifestations of a specific interaction between the acetate methyl protons and CO2 molecules are also presented." @default.
• W2017284893 created "2016-06-24" @default.
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• W2017284893 date "2005-10-21" @default.
• W2017284893 modified "2023-10-14" @default.
• W2017284893 title "High Resolution1H NMR Structural Studies of Sucrose Octaacetate in Supercritical Carbon Dioxide" @default.
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• W2017284893 doi "https://doi.org/10.1002/chem.200500215" @default.
• W2017284893 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16078290" @default.
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