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- W2017285404 abstract "The reactions of (CH3)3SnMn(CO)5 with perfluoropropene, perfluoro-2-butyne and perfluorocyclobutene are described. Similar reactions of (CH3)3MFe(CO)2(π-C5H5) (M = Si, Ge, or Sn) with perfluorocyclobutene, perfluoro-2-butyne, and 3,3,3-trifluoropropyne are described, leading to the characterization of insertion products of the types (CH3)3M(CF3)CC(CF3)Fe(CO)2(π-C5H5) and (CH3)3MC2H(CF3)Fe(CO)2(π-C5H5). When M = Sn, other products formed by the elimination of trimethyltin fluoride from 1/1 insertion products, are also formed. The mechanisms of these reactions appear to involve four-centred type transition species." @default.
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- W2017285404 title "The reactivity of metal—metal bonds VIII. A comparative study of the SiFe, GeFe and SnFe bonds, and some further reactions of the SnMn bond" @default.
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- W2017285404 doi "https://doi.org/10.1016/s0022-328x(00)91575-4" @default.
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