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- W2017287938 abstract "Conducting polyaniline (PAni)-titanium dioxide (TiO2) nanocomposites have been synthesized by the inverted emulsion polymerization method. Aqueous mixtures of aniline, a free-radical oxidant, and/or TiO2 nanoparticles (∼25 nm in diameter; mixture of anatase and rutile) are utilized to synthesize the hybrid nanocomposites. The polymerization is carried out in an organic solvent (chloroform, CHCl3) in the presence of a protonic acid (hydrochloric acid, HCl) as a dopant and an emulsifier (cetyl trimethylammonium bromide). The resultant PAni-TiO2 nanocomposites are characterized with their structural, morphological, conducting, and optical properties. SEM and TEM images represent the PAni-TiO2 nanocomposites with the diameter range of 50–200 nm. Electrical conductivities are checked by standard four-point probes method and found to be 0.38 S/cm for bulk PAni and 0.11 S/cm for PAni-TiO2 nanocomposites. UV–visible absorption shows two electronic bands at about 320 and 596 nm for bulk PAni and the blue-shifted bands with the intensity changes due to the formation of PAni-TiO2 composites. Thermogravimetric analysis reveals that the composites have a higher degradation temperature than the PAni alone. POLYM. COMPOS., 2010. © 2009 Society of Plastics Engineers" @default.
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- W2017287938 date "2009-01-01" @default.
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- W2017287938 title "Conducting polyaniline-titanium dioxide nanocomposites prepared by inverted emulsion polymerization" @default.
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- W2017287938 doi "https://doi.org/10.1002/pc.20769" @default.
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