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• W2017288214 abstract "We report the vibrationally resolved cation spectra of benzimidazole and benzotriazole, which give the respective adiabatic ionization energies (IEs) to be 67552 ± 5 cm−1 and 70474 ± 5 cm−1. Comparing these data with that of indole, one finds that the IE of these aza-aromatic bicyclic molecules increases with the number of the N atoms. Most of the active modes of the benzimidazole cation are related to the in-plane ring vibrations. In contrast, the observed spectral bands of the benzotriazole cation correspond to the out-of-plane N2–H and skeleton N1N2N3 bending vibrations. These experimental findings may be attributed to the nature and the N atoms in the five-membered ring." @default.
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• W2017288214 creator A5022596397 @default.
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• W2017288214 date "2007-04-01" @default.
• W2017288214 modified "2023-09-24" @default.
• W2017288214 title "Mass analyzed threshold ionization spectroscopy of aza-aromatic bicyclic molecules: Benzimidazole and benzotriazole" @default.
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• W2017288214 doi "https://doi.org/10.1016/j.chemphys.2007.03.002" @default.
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