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- W2017295054 abstract "L'energie d'activation de la fragmentation [C6H5OC2H5]+ → [C6H6O]+ +C2H4 est calculée. Après évaluation de la variation d'enthalpie correspondante, une structure de type phénol est déterminée pour l'ion [C6H6O]+. L'énergie d'activation de la réaction inverse est comparée à l'énergie moyenne de translation des fragments [C6H6O]+ et C2H4. L'aspect concerté ou non concerté du mécanisme de cette fragmentation est discuté. The activation energy is calculated for the fragmentation [C6H5OC2H5]+ → [C6H6O]+ +C2H4. Estimation of the enthalpy difference between the final state and the molecular ion supports the formation of a phenol-like structure for the [C6H6O]+ ion. The activation energy for backward reaction is compared with the mean kinetic energy release. Whether this is a concerted or non-concerted fragmentation is discussed." @default.
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- W2017295054 date "1978-04-01" @default.
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- W2017295054 title "Ionisation et Fragmentation en Spectrométrie de Masse. VII—Structure de l'Ion [C6H6O]+ Issu de la Décomposition du Phényléthyléther Sous Impact Electronique" @default.
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- W2017295054 doi "https://doi.org/10.1002/oms.1210130403" @default.
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