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• W2017304799 abstract "Epitaxial Fe3O4(001)/MgO(001) films obtained by reactive molecular beam epitaxy were studied using a combination of in situ scanning tunneling microscopy (STM) and monolayer 57Fe probe Conversion Electron Mössbauer Spectroscopy (CEMS). For the as-grown films the ( × )R45° surface reconstruction was observed in agreement with the earlier studies. UHV annealing considerably improves the films' surface quality (the lateral size of the terraces) but it inevitably leads to the diffusion of magnesium into the magnetite film resulting in pronounced changes of the surface structure as seen in LEED and STM. Correlation of the STM and CEMS data indicates a more complicated surface termination than the homogeneous octahedral or tetrahedral one. A charge redistribution in the surface layer evidenced by CEMS can be responsible for the surface reconstruction. Despite the surface structural and electronic modification, the presence of the Verwey transition in the surface layers is proved by low-temperature CEMS." @default.
• W2017304799 created "2016-06-24" @default.
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• W2017304799 date "2004-06-22" @default.
• W2017304799 modified "2023-10-18" @default.
• W2017304799 title "Surface Structure of Epitaxial Magnetite Fe₃O₄(001) Films: In Situ STM and CEMS Studies" @default.
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• W2017304799 doi "https://doi.org/10.1021/jp049935i" @default.
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