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• W2017311626 abstract "In this contribution we are concerned with the study of structure, topography, and surface rheological characteristics under shear conditions of monoglyceride (monopalmitin and monoolein) and milk protein (β-casein, κ-casein, caseinate, and WPI) spread monolayers at the air−water interface. Combined surface chemistry (surface film balance and surface shear rheometry) and microscopy (Brewster angle microscopy: BAM) techniques have been applied in this study to pure emulsifiers (proteins and monoglycerides) spread at the air−water interface. To study the shear characteristics of spread films, a homemade canal viscometer was used. The experiments have demonstrated the sensitivity of the surface shear viscosity (ηs) of protein and monoglyceride films at the air−water interface, as a function of surface pressure (or surface density). The surface shear viscosity was higher for proteins than for monoglycerides. In addition, ηs was higher for the globular WPI than for disordered β-casein and caseinate due to the strong forces acting on spread globular proteins. This technique makes it possible to distinguish between β-casein and caseinate spread films, with the higher ηs values for the later due to the presence of κ-casein. The ηs value varies greatly with the surface pressure (or surface density). In general, the greater the surface pressure, the greater the values of ηs. Finally, the ηs value is also sensitive to the monolayer structure, as was observed for monoglycerides with a rich structural polymorphism (i.e., monopalmitin)." @default.
• W2017311626 created "2016-06-24" @default.
• W2017311626 creator A5048714768 @default.
• W2017311626 creator A5054008068 @default.
• W2017311626 date "2004-04-20" @default.
• W2017311626 modified "2023-10-16" @default.
• W2017311626 title "Structural, Topographical, and Shear Characteristics of Milk Protein and Monoglyceride Monolayers Spread at the Air−Water Interface" @default.
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• W2017311626 doi "https://doi.org/10.1021/la036255i" @default.
• W2017311626 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15969162" @default.
• W2017311626 hasPublicationYear "2004" @default.
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