Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017313815> ?p ?o ?g. }
- W2017313815 endingPage "2119" @default.
- W2017313815 startingPage "2110" @default.
- W2017313815 abstract "Schiff bases of types 1, 2, and 3, easily prepared by the condensation of primary amines with pyridine-2-carboxaldehyde, glyoxal, or 2-acetylpyridine, respectively, are described as ligands for a copper(I) catalyst in the atom transfer polymerization of a range of methacrylates in toluene and xylene solution. Increasing the length of the alkyl group on ligands of type 1 increases the solubility of the catalyst in nonpolar solvents. The rate of polymerization increases on going from R = ethyl to propyl; however, on increasing the length of R further, we see no effect on the rate. The molecular weight distribution is narrow for all ligands where R = n-alkyl, and the number-average molecular weight (Mn) increases linearly with conversion. A decrease in rate and a loss of control are observed when branching is introduced in the α-position of the side chain. The polymerization is approximately first order in initiator, 0.90 ± 0.22, CuBr, 0.90 ± 0.13, and methyl methacrylate, 0.93 ± 0.01. Polymerization with Cu..." @default.
- W2017313815 created "2016-06-24" @default.
- W2017313815 creator A5003548374 @default.
- W2017313815 creator A5041106288 @default.
- W2017313815 creator A5057898999 @default.
- W2017313815 creator A5059949848 @default.
- W2017313815 creator A5060818239 @default.
- W2017313815 creator A5065766171 @default.
- W2017313815 creator A5067782862 @default.
- W2017313815 date "1999-03-19" @default.
- W2017313815 modified "2023-10-06" @default.
- W2017313815 title "Atom Transfer Polymerization of Methyl Methacrylate Mediated by Alkylpyridylmethanimine Type Ligands, Copper(I) Bromide, and Alkyl Halides in Hydrocarbon Solution" @default.
- W2017313815 cites W1980337066 @default.
- W2017313815 cites W1986119632 @default.
- W2017313815 cites W1988776964 @default.
- W2017313815 cites W1989014707 @default.
- W2017313815 cites W1996807119 @default.
- W2017313815 cites W1999404445 @default.
- W2017313815 cites W2004213411 @default.
- W2017313815 cites W2005680643 @default.
- W2017313815 cites W2009664167 @default.
- W2017313815 cites W201298804 @default.
- W2017313815 cites W2013749421 @default.
- W2017313815 cites W2024764154 @default.
- W2017313815 cites W2030748283 @default.
- W2017313815 cites W2032414464 @default.
- W2017313815 cites W2033531870 @default.
- W2017313815 cites W2033620725 @default.
- W2017313815 cites W2041225974 @default.
- W2017313815 cites W2046106892 @default.
- W2017313815 cites W2046772544 @default.
- W2017313815 cites W2053726121 @default.
- W2017313815 cites W2054972009 @default.
- W2017313815 cites W2056201335 @default.
- W2017313815 cites W2057193624 @default.
- W2017313815 cites W2057418295 @default.
- W2017313815 cites W2064601411 @default.
- W2017313815 cites W2071269222 @default.
- W2017313815 cites W2076525383 @default.
- W2017313815 cites W2078694248 @default.
- W2017313815 cites W2080837087 @default.
- W2017313815 cites W2082039918 @default.
- W2017313815 cites W2082138583 @default.
- W2017313815 cites W2083678749 @default.
- W2017313815 cites W2088137724 @default.
- W2017313815 cites W2088890545 @default.
- W2017313815 cites W2089023732 @default.
- W2017313815 cites W2091508865 @default.
- W2017313815 cites W2099239437 @default.
- W2017313815 cites W2317295301 @default.
- W2017313815 cites W2321290657 @default.
- W2017313815 cites W2328076269 @default.
- W2017313815 cites W2949417289 @default.
- W2017313815 cites W3023069047 @default.
- W2017313815 doi "https://doi.org/10.1021/ma981670g" @default.
- W2017313815 hasPublicationYear "1999" @default.
- W2017313815 type Work @default.
- W2017313815 sameAs 2017313815 @default.
- W2017313815 citedByCount "286" @default.
- W2017313815 countsByYear W20173138152012 @default.
- W2017313815 countsByYear W20173138152013 @default.
- W2017313815 countsByYear W20173138152014 @default.
- W2017313815 countsByYear W20173138152015 @default.
- W2017313815 countsByYear W20173138152016 @default.
- W2017313815 countsByYear W20173138152017 @default.
- W2017313815 countsByYear W20173138152018 @default.
- W2017313815 countsByYear W20173138152019 @default.
- W2017313815 countsByYear W20173138152020 @default.
- W2017313815 countsByYear W20173138152021 @default.
- W2017313815 countsByYear W20173138152022 @default.
- W2017313815 crossrefType "journal-article" @default.
- W2017313815 hasAuthorship W2017313815A5003548374 @default.
- W2017313815 hasAuthorship W2017313815A5041106288 @default.
- W2017313815 hasAuthorship W2017313815A5057898999 @default.
- W2017313815 hasAuthorship W2017313815A5059949848 @default.
- W2017313815 hasAuthorship W2017313815A5060818239 @default.
- W2017313815 hasAuthorship W2017313815A5065766171 @default.
- W2017313815 hasAuthorship W2017313815A5067782862 @default.
- W2017313815 hasConcept C132050475 @default.
- W2017313815 hasConcept C150539798 @default.
- W2017313815 hasConcept C171560689 @default.
- W2017313815 hasConcept C178790620 @default.
- W2017313815 hasConcept C185592680 @default.
- W2017313815 hasConcept C188027245 @default.
- W2017313815 hasConcept C2776300020 @default.
- W2017313815 hasConcept C2777207669 @default.
- W2017313815 hasConcept C2777935641 @default.
- W2017313815 hasConcept C2780263894 @default.
- W2017313815 hasConcept C44228677 @default.
- W2017313815 hasConcept C521977710 @default.
- W2017313815 hasConcept C544778455 @default.
- W2017313815 hasConcept C75473681 @default.
- W2017313815 hasConceptScore W2017313815C132050475 @default.
- W2017313815 hasConceptScore W2017313815C150539798 @default.
- W2017313815 hasConceptScore W2017313815C171560689 @default.
- W2017313815 hasConceptScore W2017313815C178790620 @default.
- W2017313815 hasConceptScore W2017313815C185592680 @default.
- W2017313815 hasConceptScore W2017313815C188027245 @default.