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• W2017319028 abstract "Enantioselective esterification of naproxen, 2-(6-methoxy-2-naphthyl) propionic acid, was attempted by lipases in nearly anhydrous isooctane. The nature of the alcohol affects the reactivity and enantioselectivity of the lipase from Candida cylindracea. Alcohols containing a trimethylsilyl group are highly reactive and enantioselective to the S-isomer of the acid. An optimal temperature around 65 degrees C and an enzyme concentration less than 7 mg ml-1 were proposed to resolve the racemate, with trimethylsilyl methanol as nucleophile, from a consideration of the enantiomeric ratio, the ester formation, and the resistance of mass transfer for the substrate." @default.
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• W2017319028 date "1994-04-01" @default.
• W2017319028 modified "2023-10-07" @default.
• W2017319028 title "Enantioselective esterification of racemic naproxen by lipases in organic solvent" @default.
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• W2017319028 doi "https://doi.org/10.1016/0141-0229(94)90175-9" @default.
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