Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017324420> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2017324420 endingPage "107" @default.
- W2017324420 startingPage "95" @default.
- W2017324420 abstract "Abstract The use of a new method for the determination of the absolute electrode potentials and the thermodynamics of individual ions in various solvent systems has been extended to solvents of higher dielectric constant than water, formed by adding structure-breaking urea to water. Standard e.m.f. values are reported at 25 °C for the cell: Pt,H 2 (g, 1 atm)/HX (m), water-urea/AgX, Ag, where X = C1, Br and I, in eight different aqueous solvents containing up to 40 wt.% urea. The standard e.m.f. values were used to determine not only the standard transfer Gibbs free energy Δ G ° for halogen acids from water into water-urea mixtures but also the standard absolute potentials E ° of the hydrogen and the Ag,AgX electrodes in these solvents as well as the values of Δ G t ° for the individual H + and X − ions. These data, together with the reported values of Δ G t ° (MCl), enabled us to evaluate values of E ° for the M/M + (M = Li, Na, K, Rb and Cs) electrodes, the radii of the solvated cations and the extent of their solvation in such media, and values of Δ G ° t , for the individual M + ions. The results are discussed and compared with those in various aqueous solvent systems." @default.
- W2017324420 created "2016-06-24" @default.
- W2017324420 creator A5048391708 @default.
- W2017324420 creator A5056822878 @default.
- W2017324420 date "1991-05-01" @default.
- W2017324420 modified "2023-10-16" @default.
- W2017324420 title "Gibbs free energies of transfer of individual ions from water into water-urea mixtures" @default.
- W2017324420 cites W1969338529 @default.
- W2017324420 cites W1976511540 @default.
- W2017324420 cites W1980712875 @default.
- W2017324420 cites W1982681255 @default.
- W2017324420 cites W1985157734 @default.
- W2017324420 cites W1995037773 @default.
- W2017324420 cites W1997038361 @default.
- W2017324420 cites W2002238659 @default.
- W2017324420 cites W2016485378 @default.
- W2017324420 cites W2021813352 @default.
- W2017324420 cites W2034995621 @default.
- W2017324420 cites W2045869944 @default.
- W2017324420 cites W2070358393 @default.
- W2017324420 cites W2071638797 @default.
- W2017324420 cites W2076413931 @default.
- W2017324420 cites W2082678177 @default.
- W2017324420 cites W2083060080 @default.
- W2017324420 cites W2083807289 @default.
- W2017324420 cites W2085212133 @default.
- W2017324420 cites W2087538458 @default.
- W2017324420 cites W2087599468 @default.
- W2017324420 cites W2317920107 @default.
- W2017324420 cites W2334872729 @default.
- W2017324420 cites W4231694760 @default.
- W2017324420 cites W4252781148 @default.
- W2017324420 cites W4253858453 @default.
- W2017324420 cites W2065812042 @default.
- W2017324420 doi "https://doi.org/10.1016/0040-6031(91)80415-f" @default.
- W2017324420 hasPublicationYear "1991" @default.
- W2017324420 type Work @default.
- W2017324420 sameAs 2017324420 @default.
- W2017324420 citedByCount "2" @default.
- W2017324420 crossrefType "journal-article" @default.
- W2017324420 hasAuthorship W2017324420A5048391708 @default.
- W2017324420 hasAuthorship W2017324420A5056822878 @default.
- W2017324420 hasConcept C121332964 @default.
- W2017324420 hasConcept C127413603 @default.
- W2017324420 hasConcept C145148216 @default.
- W2017324420 hasConcept C146477669 @default.
- W2017324420 hasConcept C178790620 @default.
- W2017324420 hasConcept C185592680 @default.
- W2017324420 hasConcept C2780365088 @default.
- W2017324420 hasConcept C2992078993 @default.
- W2017324420 hasConcept C2992143177 @default.
- W2017324420 hasConcept C39432304 @default.
- W2017324420 hasConcept C524765639 @default.
- W2017324420 hasConcept C87717796 @default.
- W2017324420 hasConcept C97355855 @default.
- W2017324420 hasConceptScore W2017324420C121332964 @default.
- W2017324420 hasConceptScore W2017324420C127413603 @default.
- W2017324420 hasConceptScore W2017324420C145148216 @default.
- W2017324420 hasConceptScore W2017324420C146477669 @default.
- W2017324420 hasConceptScore W2017324420C178790620 @default.
- W2017324420 hasConceptScore W2017324420C185592680 @default.
- W2017324420 hasConceptScore W2017324420C2780365088 @default.
- W2017324420 hasConceptScore W2017324420C2992078993 @default.
- W2017324420 hasConceptScore W2017324420C2992143177 @default.
- W2017324420 hasConceptScore W2017324420C39432304 @default.
- W2017324420 hasConceptScore W2017324420C524765639 @default.
- W2017324420 hasConceptScore W2017324420C87717796 @default.
- W2017324420 hasConceptScore W2017324420C97355855 @default.
- W2017324420 hasLocation W20173244201 @default.
- W2017324420 hasOpenAccess W2017324420 @default.
- W2017324420 hasPrimaryLocation W20173244201 @default.
- W2017324420 hasRelatedWork W2002988901 @default.
- W2017324420 hasRelatedWork W2042117819 @default.
- W2017324420 hasRelatedWork W2138499135 @default.
- W2017324420 hasRelatedWork W2333292111 @default.
- W2017324420 hasRelatedWork W2333325244 @default.
- W2017324420 hasRelatedWork W2407181204 @default.
- W2017324420 hasRelatedWork W2949825340 @default.
- W2017324420 hasRelatedWork W2951578338 @default.
- W2017324420 hasRelatedWork W3136100849 @default.
- W2017324420 hasRelatedWork W1644643944 @default.
- W2017324420 hasVolume "181" @default.
- W2017324420 isParatext "false" @default.
- W2017324420 isRetracted "false" @default.
- W2017324420 magId "2017324420" @default.
- W2017324420 workType "article" @default.