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- W2017331331 abstract "Hydroxyl radicals abstract hydrogen atoms from glycerol-2-phosphate with a specific rate constant of (7.0 ± 1.5) × 108 M−1s−1 forming the β-phospho radical as the major product. At physiological pH this radical undergoes a β-phosphate elimination with a rate constant ≤ 1 × 103 s−1. The β-phospho radical reacts with CU(I)-phenanthroline to produce an unstable transient with a metal-carbon σ-bond which has an absorbance similar to that of the cuprous phenanthroline complex in the visible region. This intermediate decomposes via a β-elimination of phosphate with a rate constant of 1.0 ± 1.5) × 104s−1, which was independent of the acidity in the pH range 4–9." @default.
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- W2017331331 title "Enhancement of the rate of the β-elimination of phosphate from radicals derived from glycerol-2-phosphate by Cu(I)-phenanthroline. A pulse radiolysis study" @default.
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- W2017331331 doi "https://doi.org/10.1016/0891-5849(90)90014-a" @default.
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