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- W2017334549 abstract "Despite recent insights into thermal stability of ettringite and structural changes during decomposition, a lack of knowledge on nucleation and growth mechanisms of metaettringite remained. Therefore, a better understanding of the kinetic modelling of this heterogeneous reaction was proposed. Thanks to an experimental approach allowing to check the validity of kinetic assumptions (rate-determining step, expression of the rate as dα/dt = kf(α)…), a good agreement was found between the calculated and experimental α vs. t and dα/dt vs. t kinetic curves. The reaction area of the region in which the rate-limiting step occurs was also elucidated. Finally, we demonstrated that the rate-limiting step of the growth process follows an Arrhenius law in non-isothermal conditions." @default.
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- W2017334549 date "2006-11-01" @default.
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- W2017334549 title "Kinetic modelling of the thermal decomposition of ettringite into metaettringite" @default.
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- W2017334549 doi "https://doi.org/10.1016/j.cemconres.2006.06.007" @default.
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