Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017342024> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2017342024 endingPage "19" @default.
- W2017342024 startingPage "11" @default.
- W2017342024 abstract "Abstract The rotational spectra of three isotopomers of the Ar–dimethyl sulfide (DMS) complex – normal, 34 S, and 13 C species – were measured in the frequency region from 3.7 up to 24.1 GHz by Fourier transform microwave spectroscopy. The normal species yielded 43 a -type and 79 c -type transitions. No Ar tunneling splitting was observed, while many transitions were split by the internal rotation of the two methyl tops of the DMS unit. In cases where the K -type splitting was close to that due to methyl internal-rotation, several forbidden transitions were observed that followed b -type selection rules. All of the observed transition frequencies were analyzed simultaneously using a phenomenological Hamiltonian also used in previously published work describing the Ar–dimethyl ether (DME) and Ne–DME complexes. The rotational and centrifugal distortion constants and the potential barrier height to methyl-top internal rotation, V 3 , were determined. The rotational constants were consistent with an Ar–DMS center of mass (cm) distance of 3.796 (3) A and a S–cm–Ar angle of 104.8 (2)°. The V 3 potential barrier obtained, 736.17 (32) cm −1 , was 97.8% of the DMS monomer barrier. By assuming a Lennard–Jones-type potential, the dissociation energy was estimated to be 2.4 kJ mol −1 , which was close to the value for Ar–DME, 2.5 kJ mol −1 ." @default.
- W2017342024 created "2016-06-24" @default.
- W2017342024 creator A5022434846 @default.
- W2017342024 creator A5028660159 @default.
- W2017342024 creator A5039430795 @default.
- W2017342024 creator A5055242710 @default.
- W2017342024 creator A5060233639 @default.
- W2017342024 creator A5061634903 @default.
- W2017342024 date "2009-09-01" @default.
- W2017342024 modified "2023-10-18" @default.
- W2017342024 title "Rotational spectrum of the Ar–dimethyl sulfide complex" @default.
- W2017342024 cites W1525922097 @default.
- W2017342024 cites W1969046603 @default.
- W2017342024 cites W1976074776 @default.
- W2017342024 cites W1977120477 @default.
- W2017342024 cites W1982254235 @default.
- W2017342024 cites W1983652192 @default.
- W2017342024 cites W1989848846 @default.
- W2017342024 cites W1994466201 @default.
- W2017342024 cites W1994858902 @default.
- W2017342024 cites W2001628456 @default.
- W2017342024 cites W2004334766 @default.
- W2017342024 cites W2010877000 @default.
- W2017342024 cites W2015422916 @default.
- W2017342024 cites W2025457182 @default.
- W2017342024 cites W2029841882 @default.
- W2017342024 cites W2036791420 @default.
- W2017342024 cites W2068966647 @default.
- W2017342024 cites W2077657298 @default.
- W2017342024 cites W2082269735 @default.
- W2017342024 cites W2084848425 @default.
- W2017342024 cites W2092953210 @default.
- W2017342024 cites W2093856587 @default.
- W2017342024 cites W2147682760 @default.
- W2017342024 cites W4236852356 @default.
- W2017342024 cites W4249914948 @default.
- W2017342024 doi "https://doi.org/10.1016/j.jms.2009.05.007" @default.
- W2017342024 hasPublicationYear "2009" @default.
- W2017342024 type Work @default.
- W2017342024 sameAs 2017342024 @default.
- W2017342024 citedByCount "11" @default.
- W2017342024 countsByYear W20173420242012 @default.
- W2017342024 countsByYear W20173420242015 @default.
- W2017342024 countsByYear W20173420242017 @default.
- W2017342024 countsByYear W20173420242018 @default.
- W2017342024 countsByYear W20173420242019 @default.
- W2017342024 countsByYear W20173420242021 @default.
- W2017342024 crossrefType "journal-article" @default.
- W2017342024 hasAuthorship W2017342024A5022434846 @default.
- W2017342024 hasAuthorship W2017342024A5028660159 @default.
- W2017342024 hasAuthorship W2017342024A5039430795 @default.
- W2017342024 hasAuthorship W2017342024A5055242710 @default.
- W2017342024 hasAuthorship W2017342024A5060233639 @default.
- W2017342024 hasAuthorship W2017342024A5061634903 @default.
- W2017342024 hasConcept C121332964 @default.
- W2017342024 hasConcept C156778621 @default.
- W2017342024 hasConcept C191897082 @default.
- W2017342024 hasConcept C192562407 @default.
- W2017342024 hasConcept C2778413813 @default.
- W2017342024 hasConcept C46141821 @default.
- W2017342024 hasConcept C518881349 @default.
- W2017342024 hasConcept C62520636 @default.
- W2017342024 hasConceptScore W2017342024C121332964 @default.
- W2017342024 hasConceptScore W2017342024C156778621 @default.
- W2017342024 hasConceptScore W2017342024C191897082 @default.
- W2017342024 hasConceptScore W2017342024C192562407 @default.
- W2017342024 hasConceptScore W2017342024C2778413813 @default.
- W2017342024 hasConceptScore W2017342024C46141821 @default.
- W2017342024 hasConceptScore W2017342024C518881349 @default.
- W2017342024 hasConceptScore W2017342024C62520636 @default.
- W2017342024 hasIssue "1" @default.
- W2017342024 hasLocation W20173420241 @default.
- W2017342024 hasOpenAccess W2017342024 @default.
- W2017342024 hasPrimaryLocation W20173420241 @default.
- W2017342024 hasRelatedWork W1976817450 @default.
- W2017342024 hasRelatedWork W2022270252 @default.
- W2017342024 hasRelatedWork W2062689888 @default.
- W2017342024 hasRelatedWork W2071428290 @default.
- W2017342024 hasRelatedWork W2146858094 @default.
- W2017342024 hasRelatedWork W2148263445 @default.
- W2017342024 hasRelatedWork W3045929892 @default.
- W2017342024 hasRelatedWork W4234779720 @default.
- W2017342024 hasRelatedWork W4241714927 @default.
- W2017342024 hasRelatedWork W4243661739 @default.
- W2017342024 hasVolume "257" @default.
- W2017342024 isParatext "false" @default.
- W2017342024 isRetracted "false" @default.
- W2017342024 magId "2017342024" @default.
- W2017342024 workType "article" @default.