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- W2017351520 endingPage "7156" @default.
- W2017351520 startingPage "7148" @default.
- W2017351520 abstract "Efficient electron delocalization by aromatic homoconjugated 7,7-diphenylnorbornane (DPN) in alternated homoconjugated−conjugated block copolymers and reference compounds is revealed by photophysical and electrochemical measurements. The synthesis of the polymers was achieved by Suzuki polycondensation reaction. Effective electron delocalization by DPN is demonstrated by the significant red shifts observed in the absorption and emission spectra and the variation of the energy band gap of the polymers and monomeric model compounds in comparison to a series of oligophenylenes used as references (p-quaterphenyl, p-terphenyl, and biphenyl). The electron delocalization is also clearly demonstrated by the lower oxidation potential measured for homoconjugated model compound in comparison to p-terphenyl. The results show that the electron delocalization caused by two homoconjugated aryl rings is comparable to the effect produced by one conjugated aryl ring." @default.
- W2017351520 created "2016-06-24" @default.
- W2017351520 creator A5017798531 @default.
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- W2017351520 creator A5058260842 @default.
- W2017351520 creator A5075519832 @default.
- W2017351520 creator A5090492090 @default.
- W2017351520 date "2009-08-21" @default.
- W2017351520 modified "2023-09-27" @default.
- W2017351520 title "Efficient Electron Delocalization Mediated by Aromatic Homoconjugation in 7,7-Diphenylnorbornane Derivatives" @default.
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