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- W2017360294 abstract "Tetrahydroindenes including spiro-cyclopentyl and -cyclohexyl fragments were successfully synthesized either via base-catalyzed cyclization of the respective γ-diketone or via acid-catalyzed Nazarov cyclization of the corresponding divinylketones. These substituted cyclopentadienes were metallated with nBuLi. The following reaction of the lithium salts with Cp*ZrCl3 gave three novel zirconocenes bearing spiro-cycloalkane fragments. One of these complexes, (η5-5′,6′,7′-trihydrospiro[cyclohexane-1,4′-(2-methylindenyl)])(η5-pentamethyl-cyclopentadienyl)zirconium dichloride, has been characterized by X-ray crystal structure analysis." @default.
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- W2017360294 date "2010-07-01" @default.
- W2017360294 modified "2023-09-25" @default.
- W2017360294 title "Zirconium complexes bearing η5-5′,6′,7′-trihydrospiro[cycloalkane-1,4′-indenyl] ligands" @default.
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- W2017360294 doi "https://doi.org/10.1016/j.jorganchem.2010.04.021" @default.
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