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- W2017365735 abstract "Abstract Crystallization kinetics of the copolymers of poly(ethylene terephthalate) (PET) containing 2–11 mol% of hydroquinone unit were investigated by time-resolved light scattering method. The copolyesters were prepared from PET, terephthalic acid and hydroquinone diacetate by acidolysis reaction and following polycondensation. The copolymer with 2 mol% of hydroquinone showed a spherulite growth similar to PET with a decreased crystallization rate. On the other hand, increase in the nucleation density was observed for the 6 and 8 mol% copolymers at lower crystallization temperatures and for the 11 mol% copolymer at whole range of the crystallization temperatures. The increase in the nucleation density was accompanied with reduction of the induction time and increase in the crystallization rate. As a result, the 11 mol% copolymer had a maximum crystallization rate of ca. three times as fast as that of PET. In this system, wide angle X-ray diffraction peaks of the crystal were similar to those of PET crystal. Another ordered domain was observed in the 11 mol% copolymer. However, it seems to have no direct influence on the crystallization and melting cycle." @default.
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- W2017365735 date "1997-04-01" @default.
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- W2017365735 title "Modification of crystallization properties of poly(ethylene terephthalate) by copolymerization with arylate-units: 2. Hydroquinone-containing copolymers" @default.
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- W2017365735 doi "https://doi.org/10.1016/s0032-3861(96)00771-9" @default.
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