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- W2017365787 abstract "In the cationic polymerization of isobutyl vinyl ether (IBVE) with binary initiating systems consisting of a protonic acid as an initiator and a Lewis acid as an activator/catalyst, phosphoric acid derivatives [(RO)2POOH] coupled with SnCl4 gave highly isotactic poly(IBVE)s, whereas those with a bulky substituent (R), [C4H9CH(C2H5)CH2O]2POOH (7) and (n-C10H21)2POOH (8), led to the highest isotacticity [meso dyad (m) = 86%]. In contrast, isospecificity was lower with IBVE–HCl and CF3COOH under the same conditions. From the effects of the polymerization temperature (−78 to 0 °C), it was concluded that the high isospecificity with 7 and 8 was due to an enthalpic factor. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1067–1074, 2001" @default.
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- W2017365787 date "2001-01-01" @default.
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- W2017365787 title "Stereoregulation in cationic polymerization. III. High isospecificity with the bulky phosphoric acid [(RO)2PO2H]/SnCl4 initiating systems: Design of counteranions via initiators" @default.
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- W2017365787 doi "https://doi.org/10.1002/1099-0518(20010401)39:7<1067::aid-pola1083>3.0.co;2-v" @default.
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