FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017368805> ?p ?o ?g. }

• W2017368805 endingPage "926" @default.
• W2017368805 startingPage "920" @default.
• W2017368805 abstract "The reaction of NaCp (Cp = C5H5) with excess C6F6 and excess NaH in refluxing diglyme afforded a 57% yield of 1,2,3,4-tetrakis(pentafluorophenyl)cyclopentadiene (1). Treatment of 1 with NaH in THF afforded sodium tetrakis(pentafluorophenyl)cyclopentadienide (2) in 89% yield. Reactions of 2 with M(CO)5Br (M = Mn, Re) yielded [(C6F5)4C5H]M(CO)3 complexes (3, M = Mn, 33%, and 4, M = Re, 28%). Reactions of 2 with various iron(II) salts and with CoBr2 however failed to afford the corresponding octaarylated metallocenes. Infrared spectroscopic analysis of 3 and 4 revealed an increase of 16(1) cm-1 relative to CpM(CO)3 in the A-symmetric C−O stretching frequency, suggesting that the C6F5 groups have a highly electron-withdrawing effect on the coordinated M(CO)3 moieties. Crystal structures of 1, 1·1/2C6D6, 2, and 3 display a propeller-like arrangement of the C6F5 groups. Complexes 2 and 3 show elongation of the C5(centroid)−M bond distances relative to CpMn(CO)3 and CpRe(CO)3, which is attributed to steric effects." @default.
• W2017368805 created "2016-06-24" @default.
• W2017368805 creator A5030280190 @default.
• W2017368805 creator A5032497923 @default.
• W2017368805 creator A5067452976 @default.
• W2017368805 creator A5075678548 @default.
• W2017368805 date "2001-01-27" @default.
• W2017368805 modified "2023-10-18" @default.
• W2017368805 title "Synthesis and Structure of Piano Stool Complexes Derived from the Tetrakis(pentafluorophenyl)cyclopentadienyl Ligand" @default.
• W2017368805 cites W1967460940 @default.
• W2017368805 cites W1968362223 @default.
• W2017368805 cites W1970787059 @default.
• W2017368805 cites W1974580315 @default.
• W2017368805 cites W1977240684 @default.
• W2017368805 cites W1981351372 @default.
• W2017368805 cites W1982998499 @default.
• W2017368805 cites W1983616677 @default.
• W2017368805 cites W1984218088 @default.
• W2017368805 cites W1989396366 @default.
• W2017368805 cites W1991026915 @default.
• W2017368805 cites W1991986067 @default.
• W2017368805 cites W1992302602 @default.
• W2017368805 cites W1992545987 @default.
• W2017368805 cites W1993714316 @default.
• W2017368805 cites W1996235173 @default.
• W2017368805 cites W1997337101 @default.
• W2017368805 cites W1997517034 @default.
• W2017368805 cites W1999112525 @default.
• W2017368805 cites W2004961506 @default.
• W2017368805 cites W2005679568 @default.
• W2017368805 cites W2007222528 @default.
• W2017368805 cites W2009419341 @default.
• W2017368805 cites W2018182877 @default.
• W2017368805 cites W2022115092 @default.
• W2017368805 cites W2026113142 @default.
• W2017368805 cites W2028058466 @default.
• W2017368805 cites W2031666498 @default.
• W2017368805 cites W2034005372 @default.
• W2017368805 cites W2035982081 @default.
• W2017368805 cites W2038409361 @default.
• W2017368805 cites W2040358976 @default.
• W2017368805 cites W2040630936 @default.
• W2017368805 cites W2041436151 @default.
• W2017368805 cites W2041890290 @default.
• W2017368805 cites W2049764444 @default.
• W2017368805 cites W2054498716 @default.
• W2017368805 cites W2057309790 @default.
• W2017368805 cites W2060459275 @default.
• W2017368805 cites W2061720805 @default.
• W2017368805 cites W2068190078 @default.
• W2017368805 cites W2069201213 @default.
• W2017368805 cites W2070289079 @default.
• W2017368805 cites W2070624796 @default.
• W2017368805 cites W2070910894 @default.
• W2017368805 cites W2073315041 @default.
• W2017368805 cites W2078310680 @default.
• W2017368805 cites W2079956439 @default.
• W2017368805 cites W2082220432 @default.
• W2017368805 cites W2087286052 @default.
• W2017368805 cites W2088401711 @default.
• W2017368805 cites W2095015939 @default.
• W2017368805 cites W2105467000 @default.
• W2017368805 cites W2131723111 @default.
• W2017368805 cites W2238453631 @default.
• W2017368805 cites W2323441637 @default.
• W2017368805 cites W2495720311 @default.
• W2017368805 cites W2887866975 @default.
• W2017368805 cites W2952604547 @default.
• W2017368805 cites W4240237679 @default.
• W2017368805 cites W971983378 @default.
• W2017368805 doi "https://doi.org/10.1021/om000805f" @default.
• W2017368805 hasPublicationYear "2001" @default.
• W2017368805 type Work @default.
• W2017368805 sameAs 2017368805 @default.
• W2017368805 citedByCount "34" @default.
• W2017368805 countsByYear W20173688052013 @default.
• W2017368805 countsByYear W20173688052014 @default.
• W2017368805 countsByYear W20173688052016 @default.
• W2017368805 countsByYear W20173688052017 @default.
• W2017368805 countsByYear W20173688052018 @default.
• W2017368805 countsByYear W20173688052020 @default.
• W2017368805 countsByYear W20173688052022 @default.
• W2017368805 countsByYear W20173688052023 @default.
• W2017368805 crossrefType "journal-article" @default.
• W2017368805 hasAuthorship W2017368805A5030280190 @default.
• W2017368805 hasAuthorship W2017368805A5032497923 @default.
• W2017368805 hasAuthorship W2017368805A5067452976 @default.
• W2017368805 hasAuthorship W2017368805A5075678548 @default.
• W2017368805 hasConcept C115624301 @default.
• W2017368805 hasConcept C116569031 @default.
• W2017368805 hasConcept C134121241 @default.
• W2017368805 hasConcept C155647269 @default.
• W2017368805 hasConcept C161790260 @default.
• W2017368805 hasConcept C170493617 @default.
• W2017368805 hasConcept C178790620 @default.
• W2017368805 hasConcept C181458950 @default.
• W2017368805 hasConcept C185592680 @default.
• W2017368805 hasConcept C191897082 @default.

• next