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- W2017386507 abstract "Two hitherto unidentified C19 steroids were isolated from adrenal venous blood plasma of female possum (Trichosurus vulpecula). They were 5 alpha-androstane-3 alpha,17 alpha-diol and its isomer 5 beta-androstane-3 alpha,17 alpha-diol. The compounds were isolated and identified by fractionation on paper chromatograms and HPLC, followed by gas chromatography-mass spectrometry after conversion to trimethylsilyl ethers. In adrenal venous plasma the concentrations of the 5 alpha-isomer ranged from 24-71 micrograms/100 ml, 47.5 +/- 7.7 (mean +/- SEM) and of the 5 beta-isomer 1.5-9.3 micrograms/100 ml, 5.6 +/- 1.6 (mean +/- SEM). In peripheral plasma only the 5 alpha-derivative was detectable, the highest concentration being 0.97 microgram/100 ml. The reduced steroids were not detected in the plasma of a male possum, confirming previous in vitro evidence that reduced steroids are products of the adrenocortical special zone which is found only in the female." @default.
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- W2017386507 date "1989-04-01" @default.
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- W2017386507 title "Identification of 5α-androstane-3α,17α-diol in adrenal venous plasma of female possum (Trichosurus vulpecula)" @default.
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- W2017386507 doi "https://doi.org/10.1016/0022-4731(89)90394-4" @default.
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