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- W2017388049 abstract "Treatment of α,β-unsaturated (1 and 2) and α-phenyl (3) acetals with an equimolar mixture of butyllithium and potassium tert-butoxide (Schlosser’s reagent LIC–KOR) gives α-metalated 1,3-dienes and vinyl ethers that readily react with chlorotributyltin affording (Z)-functionalized alkoxyvinylstannanes 4–6. Stille cross-coupling reaction between these reactants and allyl bromide, iodobenzene, or benzoyl chloride produces derivatives 7–13 that can be moreover converted into carbonyl compounds 14–19 according to an umpolung approach." @default.
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- W2017388049 date "2001-01-01" @default.
- W2017388049 modified "2023-10-18" @default.
- W2017388049 title "Alkoxydienylstannanes via metalation of α,β-unsaturated and α-phenyl acetals: preparation and synthetic uses in the Stille cross-coupling reaction" @default.
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- W2017388049 doi "https://doi.org/10.1039/b007500k" @default.
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