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- W2017388565 abstract "Die Spaltung einer CC-Einfachbindung im η4-Spirononadieneisen-Komplex 9 wird durch Fe2(CO)9 in siedendem Benzol initiiert und führt zum überbrückten (σ-Alkyl-π-cyclopentadienyl)eisen-Komplex 10. Dieser reagiert – wiederum unter der Einwirkung von Fe2(CO)9 – weiter zum zweikernigen „Propylfulven-Komplex”︁ 16. Die an Spirocyclopentadienen 6 beobachteten Umwandlungen unter CC-Bindungsspaltung lassen sich auf offenkettige 5,5-Dialkylcyclopentadiene 1 übertragen. Aus Kreuzungsversuchen und stereochemischen Befunden kann ein intramolekularer Reaktionsverlauf unter Wanderung der endo-Alkylgruppe abgeleitet werden. Cleavage of Unstrained CC Single Bonds in Tricarbonyliron Complexes of 5,5-Dialkyl-substituted Cyclopentadienes Cleavage of CC single bonds in η4-spirononadieneiron complex 9 is initiated by Fe2(CO)9 in boiling benzene, leading to the bridged (σ-alkyl-π-cyclopentadienyl)iron complex 10. By Fe2(CO)9 the latter is transformed to the dinuclear “propylfulvene complex” 16. The observed CC bond cleavage reactions of spirocyclopentadienes 6 can also be applied to monocyclic 5,5-dialkylcyclopentadienes 1. Crossover experiments and stereochemical results suggest an intramolecular reaction path and migration of the endo-alkyl group." @default.
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- W2017388565 date "1980-02-01" @default.
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- W2017388565 title "Die Spaltung nichtgespannter CC‐Einfachbindungen in Tricarbonyleisenkomplexen 5,5‐dialkylsubstituierter Cyclopentadiene" @default.
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- W2017388565 doi "https://doi.org/10.1002/cber.19801130212" @default.
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