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- W2017390210 abstract "(S)- and (R)-2,2′-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-binaphthyl (Xyl-H8-BINAPO) were synthesised by reacting chlorobis(3,5-dimethylphenyl)phosphine with (S)- and (R)-2,2′-dihydroxyl-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-binaphthyl, respectively. The applications of these ligands and their corresponding parent analogues in the Rh-catalysed asymmetric hydrogenation of a variety of acetamidoacrylic acids and esters provided chiral amino acid derivatives with good to excellent ee's (up to 97%)." @default.
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- W2017390210 date "2002-11-01" @default.
- W2017390210 modified "2023-10-14" @default.
- W2017390210 title "Modified BINAPO ligands for Rh-catalysed enantioselective hydrogenation of acetamidoacrylic acids and esters" @default.
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- W2017390210 doi "https://doi.org/10.1016/s0957-4166(02)00650-x" @default.
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