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- W2017398903 abstract "A novel tri-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=E2><mml:mi>n</mml:mi></mml:math>-butyl(IV) derivative of 2-thiobarbituric acid (HTBA) of formula<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=E3><mml:mrow><mml:mo>[</mml:mo><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi>n</mml:mi><mml:mtext>-</mml:mtext><mml:mtext>Bu</mml:mtext><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub><mml:mtext>Sn(TBA)</mml:mtext><mml:mo>⋅</mml:mo><mml:msub><mml:mrow><mml:mtext>H</mml:mtext></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:mtext>O</mml:mtext><mml:mo>]</mml:mo></mml:mrow></mml:math>(1) has been synthesized and characterized by elemental analysis and<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=E4><mml:mrow><mml:mn>119</mml:mn></mml:mrow><mml:mtext>Sn</mml:mtext></mml:math>-NMR and FT-IR spectroscopic techniques. The crystal structure of complex<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=E5><mml:mn mathvariant=bold>1</mml:mn></mml:math>has been determined by single crystal X-ray diffraction analysis at 120(2) K. The geometry around Sn(IV) is trigonal bipyramidal. Three<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=E6><mml:mi>n</mml:mi></mml:math>-butyl groups and one oxygen atom from a deprotonated 2-thiobarbituric ligand are bonded to the metal center. The geometry is completed with one oxygen from a water molecule. Compound<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=E7><mml:mn mathvariant=bold>1</mml:mn></mml:math>exhibits potent, in vitro, cytotoxicity against sarcoma cancer cells (mesenchymal tissue) from the Wistar rat, polycyclic aromatic hydrocarbons (PAH, benzo[a]pyrene) carcinogenesis. In addition, the inhibition caused by<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=E8><mml:mn mathvariant=bold>1</mml:mn></mml:math>, in the rate of lipoxygenase ( LOX ) catalyzed oxidation reaction of linoleic acid to hyperoxolinoleic acid, has been also kinetically and theoretically studied. The results are compared to that of cisplatin." @default.
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- W2017398903 title "Crystal Structure and Antitumor Activity of the Novel Zwitterionic Complex of tri-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=E1><mml:mi>n</mml:mi></mml:math>-Butyltin(IV) with 2-Thiobarbituric Acid" @default.
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