Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017399918> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2017399918 endingPage "111" @default.
- W2017399918 startingPage "94" @default.
- W2017399918 abstract "A gas chromatograph coupled with an atomic emission detector was used to identify and to determine the products formed on oxidation of sulfur mustard. The oxidation rate and the resulting oxidates were studied in relation to oxidant type and reaction medium parameters. Hydrogen peroxide, sodium hypochlorite, sodium perborate, potassium monopercarbonate, ammonium peroxydisulfate, potassium peroxymonosulfate (oxone), and tert-butyl peroxide were used as oxidants. Oxidations were run in aqueous media or in solvents of varying polarities. The oxidation rate was found to be strongly related to oxidant type: potassium peroxymonosulfate (oxone) and sodium hypochlorite were fast-acting oxidants; sodium perborate, hydrogen peroxide, ammonium peroxydisulfate, and sodium monopercarbonate were moderate oxidants; tert-butyl peroxide was the slowest-acting oxidant. In non-aqueous solvents, the oxidation rate was strongly related to solvent polarity. The higher the solvent polarity, the faster the oxidation rate. In the acid and neutral media, the mustard oxidation rates were comparable. In the alkaline medium, oxidation was evidently slower. A suitable choice of the initial oxidant-to-mustard concentration ratio allowed to control the type of the resulting mustard oxidates. As the pH of the reaction medium was increased, the reaction of elimination of hydrogen chloride from mustard oxidates becomes more and more intensive." @default.
- W2017399918 created "2016-06-24" @default.
- W2017399918 creator A5029599157 @default.
- W2017399918 creator A5055239045 @default.
- W2017399918 creator A5090466570 @default.
- W2017399918 date "2005-08-01" @default.
- W2017399918 modified "2023-10-18" @default.
- W2017399918 title "The GC/AED studies on the reactions of sulfur mustard with oxidants" @default.
- W2017399918 cites W1989242544 @default.
- W2017399918 cites W1991657521 @default.
- W2017399918 cites W2006043377 @default.
- W2017399918 cites W2018020235 @default.
- W2017399918 cites W2054774531 @default.
- W2017399918 cites W2056971859 @default.
- W2017399918 cites W2057540004 @default.
- W2017399918 cites W2084376130 @default.
- W2017399918 cites W2095100982 @default.
- W2017399918 cites W2332025975 @default.
- W2017399918 cites W2333148580 @default.
- W2017399918 cites W4235695670 @default.
- W2017399918 doi "https://doi.org/10.1016/j.jhazmat.2005.02.018" @default.
- W2017399918 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15876488" @default.
- W2017399918 hasPublicationYear "2005" @default.
- W2017399918 type Work @default.
- W2017399918 sameAs 2017399918 @default.
- W2017399918 citedByCount "36" @default.
- W2017399918 countsByYear W20173999182012 @default.
- W2017399918 countsByYear W20173999182013 @default.
- W2017399918 countsByYear W20173999182014 @default.
- W2017399918 countsByYear W20173999182015 @default.
- W2017399918 countsByYear W20173999182016 @default.
- W2017399918 countsByYear W20173999182017 @default.
- W2017399918 countsByYear W20173999182018 @default.
- W2017399918 countsByYear W20173999182019 @default.
- W2017399918 countsByYear W20173999182021 @default.
- W2017399918 countsByYear W20173999182022 @default.
- W2017399918 countsByYear W20173999182023 @default.
- W2017399918 crossrefType "journal-article" @default.
- W2017399918 hasAuthorship W2017399918A5029599157 @default.
- W2017399918 hasAuthorship W2017399918A5055239045 @default.
- W2017399918 hasAuthorship W2017399918A5090466570 @default.
- W2017399918 hasConcept C13965031 @default.
- W2017399918 hasConcept C178790620 @default.
- W2017399918 hasConcept C179104552 @default.
- W2017399918 hasConcept C184651966 @default.
- W2017399918 hasConcept C185592680 @default.
- W2017399918 hasConcept C2776776456 @default.
- W2017399918 hasConcept C2776832558 @default.
- W2017399918 hasConcept C2780192469 @default.
- W2017399918 hasConcept C2780471494 @default.
- W2017399918 hasConcept C2781048764 @default.
- W2017399918 hasConcept C2781443842 @default.
- W2017399918 hasConcept C518881349 @default.
- W2017399918 hasConcept C533411734 @default.
- W2017399918 hasConceptScore W2017399918C13965031 @default.
- W2017399918 hasConceptScore W2017399918C178790620 @default.
- W2017399918 hasConceptScore W2017399918C179104552 @default.
- W2017399918 hasConceptScore W2017399918C184651966 @default.
- W2017399918 hasConceptScore W2017399918C185592680 @default.
- W2017399918 hasConceptScore W2017399918C2776776456 @default.
- W2017399918 hasConceptScore W2017399918C2776832558 @default.
- W2017399918 hasConceptScore W2017399918C2780192469 @default.
- W2017399918 hasConceptScore W2017399918C2780471494 @default.
- W2017399918 hasConceptScore W2017399918C2781048764 @default.
- W2017399918 hasConceptScore W2017399918C2781443842 @default.
- W2017399918 hasConceptScore W2017399918C518881349 @default.
- W2017399918 hasConceptScore W2017399918C533411734 @default.
- W2017399918 hasIssue "1-3" @default.
- W2017399918 hasLocation W20173999181 @default.
- W2017399918 hasLocation W20173999182 @default.
- W2017399918 hasOpenAccess W2017399918 @default.
- W2017399918 hasPrimaryLocation W20173999181 @default.
- W2017399918 hasRelatedWork W1970060563 @default.
- W2017399918 hasRelatedWork W2043631778 @default.
- W2017399918 hasRelatedWork W2045253095 @default.
- W2017399918 hasRelatedWork W2069683909 @default.
- W2017399918 hasRelatedWork W2103158168 @default.
- W2017399918 hasRelatedWork W2142785751 @default.
- W2017399918 hasRelatedWork W2348336348 @default.
- W2017399918 hasRelatedWork W2359236046 @default.
- W2017399918 hasRelatedWork W2474725719 @default.
- W2017399918 hasRelatedWork W2910751213 @default.
- W2017399918 hasVolume "123" @default.
- W2017399918 isParatext "false" @default.
- W2017399918 isRetracted "false" @default.
- W2017399918 magId "2017399918" @default.
- W2017399918 workType "article" @default.