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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017402110> ?p ?o ?g. }

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• W2017402110 abstract "A novel synthetic route to (+)-manzamine A was developed. It highlights an amazingly efficient construction of a highly strained 15-membered ring across a cyclohexenone ring with the aim of installing the requisite functionalities in a completely stereocontrolled manner. Other key features include a stereoselective Diels−Alder reaction of an optically active butenolide, construction of the 15-membered ring by intramolecular Mitsunobu reaction of a nosyl amide, [3,3]-sigmatropic rearrangement of allyl cyanate for stereoselective introduction of nitrogen functionality at a sterically congested position, and a ring-closing metathesis in the presence of labile functional groups." @default.
• W2017402110 created "2016-06-24" @default.
• W2017402110 creator A5028668203 @default.
• W2017402110 creator A5064187749 @default.
• W2017402110 creator A5089248748 @default.
• W2017402110 date "2010-07-13" @default.
• W2017402110 modified "2023-10-15" @default.
• W2017402110 title "Total Synthesis of (+)-Manzamine A" @default.
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• W2017402110 doi "https://doi.org/10.1021/ja103721s" @default.
• W2017402110 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20662499" @default.
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