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- W2017405113 abstract "Abstract A microcomputer implementation of the CANDMAN© code, which calculates the equilibrial fractional inventory distributions for Fe and the acidic reagents during the course of CAN-DECON decontamination operations, is described. Using field data from CAN-DECON decontaminations of CANDU (Canada-Deuterium-Uranium) primary heat transport systems as input, the code identifies the bulk solution roles of the reagents and reveals the existence of high levels of free Fe(II) and oxalate which promotes the observed propensity towards low-solubility Fe(II)oxalate precipitation, particularly when the pH exceeds about 4. The code can also determine the minimal additions of a strong base required to buffer the pH in the range 2.5-4 so as to prevent premature termination of CAN-DECON operations if the system becomes so acidic as to promote base metal corrosion in competition with the solubilization of activity-bearing magnetite. Use of the CANDMAN code during CAN-DECON decontaminations should provide proactive operational strategies to counter the imminent precipitation of Fe(II)oxalate and the potential onset of pipework corrosion in the event that the pH departs from the ideal operational range." @default.
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- W2017405113 date "1990-01-01" @default.
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- W2017405113 title "Propensity for Fe(II)oxalate precipitation in CAN-DECON™ decontaminations of CANDU™ primary heat transport systems" @default.
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- W2017405113 doi "https://doi.org/10.1016/0306-4549(90)90042-c" @default.
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