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- W2017422975 abstract "A study of exchange singlet-singlet energy transfer was made between a series of sterically hindered ketones and α-diketones in fluid cyclohexane. The comparison of the measured rate constants of energy transfer shows them to be nearly diffusion controlled and insensitive to steric hindrance. This is argued to be a solvent cage effect. That is, the rate of energy transfer in a bimolecular collision may be sensitive to steric hindrance, but the many collisions within the cage result in a transfer efficiency of unity." @default.
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- W2017422975 title "A search for steric effects on the rate constant for exothermic singlet-singlet electronic energy transfer in fluid solution" @default.
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- W2017422975 doi "https://doi.org/10.1016/0009-2614(72)80316-6" @default.
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