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- W2017428118 abstract "A practical synthesis of trans-hydrindanone 5a from (+)-Wieland−Miescher ketone 8 is described. The target molecule 5a is a suitable precursor for the synthesis of analogues of 1α,25-dihydroxyvitamin D3 modified at C-16, C-17 or C-20. During the total synthesis it was found that hydroboration of (1,1)-ethylenedioxy-8a-methyl-1,2,3,4,6,7,8,8a-octahydronaphthalene (11) leads to a cis-decalin 13 instead of the literature reported trans-fusion." @default.
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- W2017428118 date "2000-10-01" @default.
- W2017428118 modified "2023-10-09" @default.
- W2017428118 title "Vitamin D: Enantioselective Synthesis of (3aR,4R,7aS)-4-Hydroxy-7a-methylperhydro-1-indenone, a Suitable CD-Ring Fragment" @default.
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- W2017428118 doi "https://doi.org/10.1002/1099-0690(200010)2000:20<3427::aid-ejoc3427>3.0.co;2-x" @default.
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