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- W2017431390 abstract "Abstract A variational principle is derived for the equilibrium Wigner distribution function of quantum statistical mechanics. This provides an alternative to the usual Wigner-Kirkwood expansion method of calculating quantum corrections to the structural and thermodynamic properties of systems. As an illustration, the method is applied to the second virial coefficient of a Lennard-Jones gas, and it is found that the simplest trial function gives results superior to the Wigner-Kirkwood series." @default.
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- W2017431390 date "1979-09-01" @default.
- W2017431390 modified "2023-10-16" @default.
- W2017431390 title "Variational principle for the equilibrium wigner distribution function" @default.
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- W2017431390 doi "https://doi.org/10.1016/0378-4371(79)90180-8" @default.
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