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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017444232> ?p ?o ?g. }

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• W2017444232 abstract "Identification of the local environments of the ions in a solid-state electrolyte that contribute to the ionic conductivity or remain trapped in the lattice represents a challenge for many experimental probes of structure. We show that high-resolution 17O magic angle spinning nuclear magnetic resonance (MAS NMR) spectra may be obtained even from the highly disordered, layered materials alpha-Bi4V2O11 and gamma-Bi4V1.7Ti0.3O10.85, in which the different oxide sites in the lattice may be distinguished. The sites responsible for anionic conduction were determined directly from the variable-temperature 17O NMR spectra, and correlation times for motion were estimated. Double-resonance 17O/51V NMR methods were used as confirmation of the assignments of the resonances and as a second experimental probe of motion that is sensitive to mobility involving oxide ion hops between the same crystallographic sites." @default.
• W2017444232 created "2016-06-24" @default.
• W2017444232 creator A5001567618 @default.
• W2017444232 creator A5088159296 @default.
• W2017444232 date "2002-08-23" @default.
• W2017444232 modified "2023-10-13" @default.
• W2017444232 title "Probing Oxygen Motion in Disordered Anionic Conductors with ¹⁷ O and ⁵¹ V MAS NMR Spectroscopy" @default.
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• W2017444232 doi "https://doi.org/10.1126/science.1074130" @default.
• W2017444232 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12130662" @default.
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