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• W2017444916 abstract "The binding ability of Zn-tetraarylporphyrins with two, four and eight 4-carbazolylphenyl-1,2,3-triazole end groups towards 1,4-diazabicyclo[2.2.2]octane, pyridine and 1,2,3-triazole in toluene was studied by spectrophotometric and 1H NMR titration. It was determined that due to a good geometric match of the ligand size to the size of the intramolecular cavities of the porphyrinic receptor, and by the existence of additional π–π and/or hydrogen bonding interactions between the ligand and the triazole fragments of the porphyrin, the Zn-tetraarylporphyrin with eight 4-carbazolylphenyl-1,2,3-triazole end groups could be used as an effective receptor for 1,2,3-triazole and other small heterocycles such as pyridine. Taking into account the fact that binding is accompanied by a clear and easily identifiable response in the UV–vis spectra of the reaction mixture, this metalloporphyrin could be considered as a molecular optical sensing device for small heterocyclic substrates." @default.
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• W2017444916 date "2012-12-12" @default.
• W2017444916 modified "2023-10-16" @default.
• W2017444916 title "Binding ability of Zn-tetraarylporphyrins with two, four and eight 4-(4-(3,6-bis(<i>t</i>-butyl)carbazol-9-ylphenyl)-1,2,3-triazole end groups towards N-containing substrates of different nature" @default.
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• W2017444916 doi "https://doi.org/10.1080/10610278.2012.741687" @default.
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