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- W2017447457 abstract "High-resolution infrared spectra have been remeasured for the ν2, 2ν2, and ν4 bands of 4NH3 using a vacuum grating infrared spectrometer and a diode laser spectrometer. Far-infrared spectra of 14NH3 have been measured with microwave accuracy in the 700–1100 GHz region by employing a submillimeter wave spectrometer (RAD) with acoustic detection. The pure inversion and inversion-rotation transition frequencies in the ν2 excited state of 14NH3 have been determined for the first time. The vibration-inversion-rotation Hamiltonian of ammonia [Špirko, Stone, and Papoušek, J. Mol. Spectrosc. 60, 159–178 (1976)] has been used for a precise parameterization of the energy levels of ammonia. The ground state rotational and centrifugal constants of 14NH3 have been determined using a modified method of combination differences. Coriolis and l-type interactions between ν2, ν4, 2ν2, ν2 + ν4, and 3ν2 states have been analyzed and the band parameters have been obtained which reproduce the transition frequencies within the accuracy of the experimental data." @default.
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- W2017447457 date "1980-02-01" @default.
- W2017447457 modified "2023-10-17" @default.
- W2017447457 title "Coriolis and l-type interactions in the ν2, 2ν2, and ν4 states of 14NH3" @default.
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- W2017447457 doi "https://doi.org/10.1016/0022-2852(80)90226-x" @default.
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