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• W2017449706 abstract "Overcoming high-temperature (HT) two-dimensional gas chromatography (GC×GC) limits is critical for the analysis of heavy hydrocarbons, particularly those contained in heavy petroleum fractions. To reach this goal, HT-GC×GC analysis was adapted from HT-GC Simulated Distillation (HT-GC SimDist) operating conditions as this analysis embraces compounds whose boiling point ranges from 35 °C to 700 °C and from a previous study that enabled the elution of linear alkane nC60 and tetraaromatic compounds by HT-GC×GC. This paper shows that HT-GC×GC analysis using CO2 cryogenic modulator and short wide bore columns with a thin film of stationary phase allows the elution of linear alkanes up to nC68 (641 °C) as well as of highly aromatic hydrocarbons like coronene. Furthermore, compared to previous studies, an on-column injector was used to reduce discrimination of high boiling point compounds." @default.
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• W2017449706 date "2012-03-01" @default.
• W2017449706 modified "2023-09-25" @default.
• W2017449706 title "Overcoming the high-temperature two-dimensional gas chromatography limits to elute heavy compounds" @default.
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• W2017449706 doi "https://doi.org/10.1016/j.chroma.2012.01.030" @default.
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